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11.
《International Journal of Hydrogen Energy》2022,47(3):1752-1764
Subsurface hydrogen (H2) storage in geological formations is of growing interest for decarbonization. However, there is a knowledge gap in understanding the multiphase flow involved in this process, which can have a significant impact on the recovery performance of H2. Therefore, a full-compositional modeling study was conducted to analyze potential issues and to understand the fundamental hydrodynamic mechanisms of H2 storage. We performed a range of 2D vertical simulations at the decametre scale with a very fine cell size (0.1 m) to observe the detailed flow behaviour of H2 with carbon dioxide (CO2) as cushion gas in various flow regimes. Issues such as viscous instability, capillary bypassing, gas trapping and gravity segregation are analysed here. To generalize our calculations, we have validated and applied the scaling theory in the context of subsurface H2 storage. Since this study is focused on the hydrodynamic behaviour, three dimensionless groups, including aspect factor, capillary/viscous ratio and gravity/viscous ratio were identified to correlate recovery performance between various scales in a fixed heterogeneous system. It was found that H2 could infiltrate the cushion gas in the proximity of the injectors, meaning that CO2 is not displaced away from the injectors in a piston-like fashion. As a result, the purity of the back produced H2 is much degraded, particularly in a viscous-dominated scenario. On the other hand, the injected H2 mostly accumulates at the top forming a highly restricted mixing zone with CO2 in the gravity-dominated case. The recovery performance is therefore much improved in this case. Although the gas distribution can be significantly altered by capillary forces leading to bypassed zones, the recovery performance of H2 is hardly influenced. This is because the back-produced H2 recovery is not dependent on the sweep efficiency of the gas. H2 can be back produced following the same paths which were formed during injection. 相似文献
12.
Understanding on the hydrogen detection of plasma sprayed tin oxide/tungsten oxide (SnO2/WO3) sensor
《International Journal of Hydrogen Energy》2022,47(33):15120-15131
The plasma spray technique was well proven in producing metal oxide based gas sensors in the last two decades using different powder feedstocks. However, limited research was made to fabricate hydrogen gas sensor from tin oxide layer coated over tungsten oxide layer. This paper attempts to interpret the hydrogen gas sensing performances of plasma sprayed coating derived by depositing tin oxide layer over tungsten oxide (SnO2/WO3) layer. Plasma sprayed SnO2/WO3 sensor showed maximum response of 90% at 150 °C in contrast to stand-alone WO3 (89% at 350 °C) and stand-alone SnO2 (89% at 250 °C). The lower operating temperature of SnO2/WO3 sensor without compromising gas response was attributed to the WO3–SnO2 hetero-junction. SnO2/WO3 sensor showed selective sensing towards hydrogen with respect to carbon monoxide and methane gases. This sensor also possessed repeatable characteristics after 39 days from the initial measurement. In a nut-shell, plasma spayed SnO2/WO3 sensor showed stability of base resistance, repeatability after successive response and recovery cycles, selective sensing towards 500 ppm H2 with significant magnitude of gas response of 90%, response time of 35 s and recovery time of 269 s at a temperature of 150 °C. 相似文献
13.
《International Journal of Hydrogen Energy》2022,47(63):27279-27292
This study assesses a sustainable solution to greenhouse gases (GHGs) mitigation using constructed wetland-microbial fuel cells (CW-MFC). Roots of wetland plant Acorus Calamus L. are placed in biological anode to better enable anode microorganisms to obtain rhizosphere secretion for power improvement. Three selected cathode materials have a large difference in GHG emissions, and among them, carbon fiber felt (CFF) shows the lowest emissions of methane and nitrous oxide, which are 0.77 ± 0.04 mg/(m2·h) and 130.78 ± 13.08 μg/(m2·h), respectively. The CFF CW-MFC achieves the maximum power density of 2.99 W/m3. As the influent pH value is adjusted from acidic to alkaline, the GHGs emissions are reduced. The addition of Ni inhibits GHGs emission but decreases the electricity, the power density is reduced to 1.09 W/m3, and the methane and nitrous oxide emission fluxes decline to 0.20 ± 0.04 mg/(m2·h) and 15.49 ± 1.86 μg/(m2·h), respectively. Low C/N ratio reduces methane emission, while high C/N ratio effectively inhibits nitrous oxide emission. At the influent pH 8 and C/N = 5:1, the methane emission flux is approximately 10.60 ± 0.27 mg/(m2·h), and the nitrous oxide emission flux is only 10.90 ± 1.10 μg/(m2·h). Based on the above experimental results by controlling variable factors, it is proposed that CW-MFC offers an environment-friendly solution to regulate GHG emissions. 相似文献
14.
15.
Pengcheng Su Huiyu Tang Miaomiao Jia Yanshan Lin Wanbin Li 《American Institute of Chemical Engineers》2022,68(5):e17576
Metal–organic framework (MOF) membranes are promising for efficient separation applications. However, the uncontrollable pathways at atomic level impede the further development of these membranes for molecular separation. Herein we show that vapor linker exchange can induce partial amorphization of MOF membranes and then reduce their transport pathways for precisely molecular sieving. Through exchanging MOF linkers by incoming ones with similar topology but higher acidity, the resulted metal-linker bonds with lower strength cause the transformation of MOF membranes from order to disorder/amorphous. The linker exchange and partial amorphization can narrow intrinsic apertures and conglutinate grain boundary/crack defects of membranes. Because of the formation of ultra-microporous amorphous phase, the MOF composite membrane shows competitive H2/CO2 selectivity up to 2400, which is about two orders of magnitude higher than that of conventional MOF membranes, accompanied by high H2 permeance of 13.4 × 10−8 mol m−2 s−1 Pa−1 and good reproducibility and stability. 相似文献
16.
《International Journal of Hydrogen Energy》2022,47(15):9139-9155
Methane tri-reforming combines steam reforming, dry reforming and partial oxidation of methane in a single reactor. The heat generated by the exothermic partial oxidation of methane can be used to supply the energy for the other two endothermic reactions (dry and steam reforming of methane). The thermoneutral condition allows the use of a tri-reformer with a simpler reactor structure since no external heat supply is necessary. Thermodynamic analysis of the thermoneutral reactor was performed using Gibbs free energy minimization approach. Conventional tri-reformers have heat and mass management problems. We developed a novel tri-reformer concept that utilizes proper distribution of O2 gas to the reactor to address the problems. The optimization of the proposed reactor was performed with the objective function of minimizing total annual cost. Maintaining the peak temperatures by adjusting the O2 flow rate at the distribution point along the reactor was shown to provide good load flexibility for the change in methane flow rate. 相似文献
17.
《Ceramics International》2022,48(2):1494-1511
The application of insulation materials in buildings and energy storage facilities is gaining global attention to reduce energy consumption, heat loss, and CO2 emissions. Given the high insulation performance, glass foam is gaining popularity replacing combustible, high energy-consuming, and costly conventional insulation materials. The industrial process of glass foam manufacturing is an energy-consuming and non-ecofriendly process which requires the annealing of glass around its melting temperature. Therefore, researchers have developed powder sintering and gel casting methods to sinter glass foam mix at a temperature slightly above its glass transition point. However, research findings on these two methods are scattered because of the different parameters being used by researchers. The properties and performances of glass foam depend on the processing parameters, especially on the materials design and sintering conditions. Therefore, this study aimed to provide a comprehensive review on the key parameters for material selection and sintering of glass foams and provide necessary guidelines for the best practice and a direction for future research. Moreover, this review covers the current strategies and challenges associated with the powder sintering and gel casting methods including their sustainability and environmental performance. 相似文献
18.
教传艳 《计算机测量与控制》2022,30(2):124-128
针对当前柴油机废气再循环冷却控制系统受到时滞问题影响,导致系统开度走势与设定走势不一致、废气再循环效果差的问题,提出基于自适应LS-SVM的柴油机废气再循环冷却控制系统;以AT89C51单片机40针作为电控单元核心部件,利用位置传感器向系统发送负载信号,利用温度传感器来传输信号并反馈至D/A转换器;在D/A转换器中,反馈信号以串行或并行方式进入寄存器,并在转换后输出电流电压,控制系统阀门在排气再循环时的开启;伺服泵采用冷却系统,为系统提供液压动力源;利用自适应LS-SVM原理计算柴油机废气再循环冷却控制目标边界值,在最小二乘支持向量机基础上,利用求解线性方程组进行优化,消除了控制误差;根据控制差的大小,调整控制系统的输出值;由试验结果可知,该系统开度走势与设定开度走势一致,且与设定开度误差为1开度,说明使用该系统具有良好稳态特性,有效克服了系统中时滞问题,废气再循环效果较好。 相似文献
19.
20.
《International Journal of Hydrogen Energy》2022,47(27):13213-13225
The paper presents a technical, economic and environmental analyses of a chamber furnace used to heat the charge before forging. The energy efficiency of the furnace before the modernization was 18%, after the modernization it was 31% (partial modernization due to large financial outlays). Other variants were also analysed: complete modernization, the variant of furnace modernization with 30% hydrogen content in the gas and the variant with 100% hydrogen as fuel. The analyses showed that with the current gas price (0.025 EUR/kWh) and the price of emission allowances (nearly 60 EUR/MgCO2) and 100 cycles/year, the difference in Net Present Value (NPV) before base variant and partial modernization is around 900,000 EUR and before base variant and full modernization is 1,200,000 EUR. The introduction of the gas and 30% of hydrogen co-combustion option versus the base scenario option for 150 cycles per year results in a NPV difference of at least 2 million EUR. The option of 100% hydrogen as a fuel is the most advantageous from the point of view of reducing CO2 emissions - it is largely influenced by the rising prices of CO2 emission allowances. 相似文献